When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CF3CCl2O2_Jemi-Alade(1991)_298K_220-290nm(resc).txt |
NAME: | 1,1-dichloro-2,2,2-trifluoroethylperoxy radical |
FORMULA: | CF3CCl2O2 |
AUTHOR(YEAR): | Jemi-Alade(1991) |
T: | 298K |
λ: | 220-290nm(resc) |
BIBLIOGRAPHY: |
A.A. Jemi-Alade, P.D. Lightfoot, and R Lesclaux, "Measurements of the UV absorption cross-sections of CF3CCl2O2, CF3CHFO2, CFCl2CH2O2, and CF2ClCH2O2 in the gas phase",
Chem. Phys. Lett. 179, 119-124 (1991);
DOI: 10.1016/0009-2614(91)90301-O
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COMMENTS: | Flash photolysis technique coupled with UV absorption spectrometry; photolysis of Cl2 in the presence of CF3CHCl2 and synthetic air The original values have been rescaled using the factor 4.58/4.8 to incorporate the value of σ(CH3O2) = 4.58×10-18 cm2 molecule-1 at 240 nm recommended by P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry," Atmos. Environ. 26A, 1805-1961 (1992) |
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